Redox reactions
A redox reaction is a reaction involving a reduction reaction and an oxidation reaction. The meaning of the oxidation reaction and the reduction reaction develops in accordance with the development of chemistry. Reduction reactions and oxidation reactions occur in everyday life, such as combustion reactions, vinegar making from alcohol, glucose breaking events in the body, iron filings, and so on.
Understanding Redox Reactions
Initially the concept of reduction and oxidation (redox) is limited to reactions involving the release and binding of oxygen. The oxidation reaction is the reaction of oxygen binding by a substance.
A redox reaction is a reaction involving a reduction reaction and an oxidation reaction. The meaning of the oxidation reaction and the reduction reaction develops in accordance with the development of chemistry. Reduction reactions and oxidation reactions occur in everyday life, such as combustion reactions, vinegar making from alcohol, glucose breaking events in the body, iron filings, and so on.
Understanding Redox Reactions
Initially the concept of reduction and oxidation (redox) is limited to reactions involving the release and binding of oxygen. The oxidation reaction is the reaction of oxygen binding by a substance.
Oxidation and Redox Reactions
The more universal concept of redox reactions to explain reactions involving covalent compounds is the concept of redox reactions based on changes in oxidation numbers.
The redox reactions that are difficult to explain with the concept of oxygen and the concept of electrons can be easily explained using the concept of oxidant numbers.
Oxidation number
The oxidation or oxidation state of an element is a positive or negative integer given to an element in forming a compound. The oxidation number of an element is determined by considering the following.
A) The ionic compound
The oxidation number of elements in monoatomic ions is the real charge of the compound ions.
Example:
The NaCl compound, formed from Na + and Cl- ions, then the oxidation number of Na atoms in NaCl is +1, and the oxidation number Cl is -1.
B) Covalent compounds
The thing to note in determining the oxidation number in the covalent compound is the price of the electronegativity scale of each of the constituent atoms.
The atomic elements having a higher electronegative scale value indicate that the attraction of the atoms to the bonding electron pair is stronger. Because it is stronger to attract an electron pair, it becomes negative, and therefore the oxidation number is given a negative number. Atoms that have lower electronegativity prices are given positive oxidation numbers.
Example:
HCl compounds are formed from hydrogen atoms (electronegativity H = 2.0) and chlorine atoms (electronegativity Cl = 3.0) by using a common electron pair. These joint electrons are more attracted to Cl atoms, then the chlorine atom is oxidized -1, whereas the hydrogen atom is given the +1 oxidation number.
Determination of oxidation number
To determine the oxidation number of suatau atoms in a compound can be used some of the following provisions.
1. The oxidation number of free element (not compound) is 0 (zero).
2. The number of algebraic oxidation numbers of all atoms in a compound is 0 (zero).
3. The number of algebraic oxidation numbers of all atoms in a polyatomic ion is equal to the charge of the ion.
4. Certain elements in forming compounds have certain oxidation numbers, for example:
Group IA atoms (Li, Na, K, Rb, Cs, and Fr) in the compound have +1 oxidation states.
Group IIA atoms (Be, Mg, Ca, Sr, and Ba) in the compound have a +2 oxidation number.
Class IIIA (B, Al, and Ga) atoms in the compound have +3 oxidation numbers.
The hydrogen atom (H) in the compound generally has a +1 oxidation number, except in the metal hydride. Metal hydrides are compounds formed from metal and hydrogen elements. In metal hydrides, such as LiH, NaH, CaH2, MgH2, and AlH3, the hydrogen atom is given a -1 oxidation number.
The oxygen atom (O) in the compound generally has an oxidation number of -2, except in the peroxide compound and OF2.
In peroxides, such as H2O2, Na2O, and BaO, the oxygen atoms are given the oxidation number -1, whereas at OF2 is given a +2 oxidation number
The more universal concept of redox reactions to explain reactions involving covalent compounds is the concept of redox reactions based on changes in oxidation numbers.
The redox reactions that are difficult to explain with the concept of oxygen and the concept of electrons can be easily explained using the concept of oxidant numbers.
Oxidation number
The oxidation or oxidation state of an element is a positive or negative integer given to an element in forming a compound. The oxidation number of an element is determined by considering the following.
A) The ionic compound
The oxidation number of elements in monoatomic ions is the real charge of the compound ions.
Example:
The NaCl compound, formed from Na + and Cl- ions, then the oxidation number of Na atoms in NaCl is +1, and the oxidation number Cl is -1.
B) Covalent compounds
The thing to note in determining the oxidation number in the covalent compound is the price of the electronegativity scale of each of the constituent atoms.
The atomic elements having a higher electronegative scale value indicate that the attraction of the atoms to the bonding electron pair is stronger. Because it is stronger to attract an electron pair, it becomes negative, and therefore the oxidation number is given a negative number. Atoms that have lower electronegativity prices are given positive oxidation numbers.
Example:
HCl compounds are formed from hydrogen atoms (electronegativity H = 2.0) and chlorine atoms (electronegativity Cl = 3.0) by using a common electron pair. These joint electrons are more attracted to Cl atoms, then the chlorine atom is oxidized -1, whereas the hydrogen atom is given the +1 oxidation number.
Determination of oxidation number
To determine the oxidation number of suatau atoms in a compound can be used some of the following provisions.
1. The oxidation number of free element (not compound) is 0 (zero).
2. The number of algebraic oxidation numbers of all atoms in a compound is 0 (zero).
3. The number of algebraic oxidation numbers of all atoms in a polyatomic ion is equal to the charge of the ion.
4. Certain elements in forming compounds have certain oxidation numbers, for example:
Group IA atoms (Li, Na, K, Rb, Cs, and Fr) in the compound have +1 oxidation states.
Group IIA atoms (Be, Mg, Ca, Sr, and Ba) in the compound have a +2 oxidation number.
Class IIIA (B, Al, and Ga) atoms in the compound have +3 oxidation numbers.
The hydrogen atom (H) in the compound generally has a +1 oxidation number, except in the metal hydride. Metal hydrides are compounds formed from metal and hydrogen elements. In metal hydrides, such as LiH, NaH, CaH2, MgH2, and AlH3, the hydrogen atom is given a -1 oxidation number.
The oxygen atom (O) in the compound generally has an oxidation number of -2, except in the peroxide compound and OF2.
In peroxides, such as H2O2, Na2O, and BaO, the oxygen atoms are given the oxidation number -1, whereas at OF2 is given a +2 oxidation number
Redox reactions
A redox reaction is a reaction involving a reduction reaction and an oxidation reaction. The meaning of the oxidation reaction and the reduction reaction develops in accordance with the development of chemistry. Reduction reactions and oxidation reactions occur in everyday life, such as combustion reactions, vinegar making from alcohol, glucose breaking events in the body, iron filings, and so on.
Understanding Redox Reactions
Initially the concept of reduction and oxidation (redox) is limited to reactions involving the release and binding of oxygen. The oxidation reaction is the reaction of oxygen binding by a substance.
A redox reaction is a reaction involving a reduction reaction and an oxidation reaction. The meaning of the oxidation reaction and the reduction reaction develops in accordance with the development of chemistry. Reduction reactions and oxidation reactions occur in everyday life, such as combustion reactions, vinegar making from alcohol, glucose breaking events in the body, iron filings, and so on.
Understanding Redox Reactions
Initially the concept of reduction and oxidation (redox) is limited to reactions involving the release and binding of oxygen. The oxidation reaction is the reaction of oxygen binding by a substance.
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